Award Abstract #0093783
PECASE: Elucidation of Reaction Mechanisms and Evaluation of Photoactivated Periodate as an Advanced Oxidation Technology

NSF Org:	CBET Division of Chemical, Bioengineering, Environmental, and Transport Systems
Initial Amendment Date:	January 29, 2001
Latest Amendment Date:	May 22, 2007
Award Number:	0093783
Award Instrument:	Continuing grant
Program Manager:	Paul L. Bishop CBET Division of Chemical, Bioengineering, Environmental, and Transport Systems ENG Directorate for Engineering
Start Date:	September 1, 2001
Expires:	August 31, 2008 (Estimated)
Awarded Amount to Date:	$436126
Investigator(s):	Linda Weavers weavers.l@osu.edu (Principal Investigator)
Sponsor:	Ohio State University Research Foundation 1960 KENNY RD Columbus, OH 43210 614/292-3732
NSF Program(s):	ENVIRONMENTAL IMPLICATIONS
Field Application(s):	0118000 Pollution Control
Program Reference Code(s):	EGCH, 9251, 9231, 9197, 9187, 1359, 1187, 1076, 1045, 015E
Program Element Code(s):	1179

ABSTRACT

Toxic contaminants continue to persist in the environment, threatening the health of humans and ecosystems. For example, the United States has a stock pile of 30,600 tons of chemical warfare agents (NRC, 1996). These chemical agents are extremely hazardous and the Army is under law to dispose of the stockpile by 2007. However, the baseline technology, incineration, faces considerable organized opposition due to air pollution concerns forcing the Army to look at alternative technologies. Advanced oxidation processes (AOPs) show considerable promise as a potential solution to these problems because, similar to incineration, pollutants are destroyed eliminating future risk, yet no air pollution is formed. However, development of AOPs that are less costly and more effective for the degradation of pollutants at relatively high aqueous concentrations is needed.

In this project, photoactivated periodate will be explored generally as a potential AOP and particularly for the destruction of chemical warfare agents. This study will investigate the kinetics and mechanism of destruction of a range of pollutants with differing expected reactivities with radicals formed by photoactivated periodate. Detailed studies of the organic decomposition products and inorganic iodine stable and transient intermediates formed will be used to gain insight into the pathways of degradation.

For the education component of this proposal, the PI plans to stimulate learning by emphasizing the bridges between research and teaching and incorporating real world case studies into courses. Mentoring school aged and pre-freshman female students is another important component to be cultivated by involvement in summer workshops at OSU. The Women In Engineering Summer Workshop brings 50 pre-freshmen women to campus in the summer to orient them to engineering principles and the different disciplines of engineering. Hosted for a day of environmental engineering, they are guided in an experiment to determine nitrate and phosphate removal by wetlands. With funds from this proposal, the PI will develop a similar week-long workshop for eighth-grade girls. Undergraduate students and faculty will be recruited to participate in guiding girls while they explore various facets of engineering. Both mentoring activities are expected to increase enrollment and retention of women in engineering.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

L-. H. Chia and L. K. Weavers. "Photoactivated Periodate as a Novel Advanced Oxidation Technology: Reaction Kinetics and Mechanism of Photoactivated Periodate with 4-Chlorophenol in Acidic Solution," The Eighth International Conference on Advanced Oxidation Technologies for Water and Air Remediation, Toronto, Canada, November 17-21, 2002, 2002, p. 104.

Liang-Hiong Chia, Xueming Tang and Linda K. Weavers. "Kinetics and Mechanism of 4-Chlorophenol Degradation by Photoactivated Periodate in Acidic Solution," Environmental Science and Technology, v.38, 2004, p. 6875.

Paolo A. G. Sivilotti and Murat Demirbas. "Introducing Middle School Girls to Fault Tolerant Computing," 34th Technical Symposium on Computer Science Education (SIGCSE), 2003, p. 327.

X. M. Tang and L. K. Weavers. "Applying Photoactivated Periodate as a Technology to Decompose Hydrolysates of Chemical Warfare Agents," The Eleventh International Conference on Advanced Oxidation Technologies for Treatment of Water, Air, and Soil (AOTs-11), Chicago, IL, October 24-27., 2005, p. abstract.

X. M. Tang and L. K. Weavers. "Using Photoactivated Periodate to Decompose TOC from Hydrolysates of Chemical Warfare Agents," Journal of Photochemistry and Photobiology A: Chemistry, v.194, 2008, p. 212.

X. M. Tang and L. K. Weavers. "Decomposition of Hydrolysates of Chemical Warfare Agents using Photoactivated Periodate," Journal of Photochemistry and Photobiology A: Chemistry, v.187, 2007, p. 311.

X. Tang and L. K. Weavers. "Photoactivated Periodate as a technology to degrade hydrolysates of chemical warfare agents," 228th National Meeting of the American Chemical Society, Division of Environmental Chemistry, Philadelphia, PA, August 22-26, 2004, 2004, p. 65.

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