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Award Abstract #0102467
NER: Self-Assembled Nanostructures with Macroscopic Polar Order and Directed Paths of Conjugation

| NSF Org: |
DMR
Division of Materials Research
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| Initial Amendment Date: |
July 24, 2001 |
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| Latest Amendment Date: |
July 24, 2001 |
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| Award Number: |
0102467 |
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| Award Instrument: |
Standard Grant |
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| Program Manager: |
David Nelson
DMR Division of Materials Research
MPS Directorate for Mathematical & Physical Sciences
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| Start Date: |
July 15, 2001 |
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| Expires: |
June 30, 2002 (Estimated) |
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| Awarded Amount to Date: |
$99575 |
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| Investigator(s): |
Colin Nuckolls cn37@columbia.edu (Principal Investigator)
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| Sponsor: |
Columbia University
2960 Broadway
NEW YORK, NY 10027 212/854-6851
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| NSF Program(s): |
DMR SHORT TERM SUPPORT, NANOSCALE: EXPLORATORY RSRCH
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| Field Application(s): |
0106000 Materials Research
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| Program Reference Code(s): |
AMPP, 9162, 1762, 1676
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| Program Element Code(s): |
1712, 1676
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ABSTRACT

This Nanoscale Exploratory Research (NER) project aims to design, synthesize, and assemble organic molecules. Two specific areas will be addressed. Firstly, by creating new types of molecules (for example that form discotic liquid crystals) with specific noncovalent interactions, a scheme for interfacing self-assembled, organic conductors with gold surfaces will be achieved. Secondly, these interconnections will serve to orient dipolar columns assembled on surfaces creating macroscopic polar order, which is a prerequisite for creating nanodevices for ferroelectric, piezoelectric, and pyroelectric applications.
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A major goal of nanotechnology is the creation of molecular systems such as one dimensional conductors from discotic liquid crystals that can serve as a springboard for multidisciplinary research aimed at developing nanoscale devices. The types of devices to be explored include piezoelectric, ferroelectric, pyroelectric, and nonlinear optical. Students trained in these areas will be compete well for academic and industrial jobs.
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