Pradeep P. Fulay
ECCS Division of Electrical, Communications and Cyber Systems
ENG Directorate for Engineering
Start Date:
October 1, 2002
Expires:
September 30, 2007 (Estimated)
Awarded Amount to Date:
$1577000
Investigator(s):
Chang-Beom Eom eom@engr.wisc.edu (Principal Investigator)
Venkat Chandrasekhar (Co-Principal Investigator) Mark Rzchowski (Co-Principal Investigator) Daniel van der Weide (Co-Principal Investigator) Xiaoqing Pan (Co-Principal Investigator)
Sponsor:
University of Wisconsin-Madison
21 North Park Street
MADISON, WI 53715 608/262-3822
NSF Program(s):
ELECTRONIC/PHOTONIC MATERIALS, ELECT, PHOTONICS, & DEVICE TEC, GRANT OPP FOR ACAD LIA W/INDUS
This proposal was received in response to the Nanoscale Science and Engineering Initiative, Program Solicitation NSF 01-157, in the NIRT category. The proposal focuses on understanding intrinsic phenomena governing spin transport at the nanoscale, and the development of new methods for its manipulation for future spin-controlled, magneto-electronic, devices. It addresses one of the most exciting aspects of current research on next-generation electronic devices: the manipulation of spin, rather than only electrical charge. The advantages of these magnetoelectronic devices include nonvolatility, faster switching in static memory elements, and higher density due to a simpler device structure. These issues become even more important as technology drives device sizes toward the nanoscale, where new fundamental physical effects emerge that alter spin transport, as well as high-frequency dynamics and switching times.
An understanding of these issues at the nanoscale requires single-crystal magnetic heterostructures with atomically-sharp interfaces, patterned to nanometer dimensions. This proposal probes nanoscale spin transport phenomena in epitaxial magnetic oxide nanostructures grown with atomic-layer control, whose magnetic, electronic, and interfacial properties are tuned at will. Layers with defined electronic, magnetic, and morphological characteristics positioned with atomic-layer control in epitaxial systems are used to address crucial fundamental questions in magnetic nanostructures.
This research program consists of 1) design, growth, and characterization of epitaxial magnetic oxide heterostructures with atomic layer control by pulsed laser deposition with in-situ real-time structural analysis 2) high-resolution and analytical TEM to determine atomic structure and electronic properties of the interfaces; 3) nanoscale patterning of novel magnetic heterostructures below 50 nm; 4) scanning probe measurements of topography and local electronic properties; 5) education and outreach efforts with a focus on introducing young people to modern, multidisciplinary science and technology, using the research direction as a vehicle.
The multidisciplinary, multiuniversity/industry team consists of members working in Materials Science, Physics, Electrical Engineering, and device development. Research, education, and outreach all follow the theme of nanoscale structures, novel phenomena, and spin transport control. This work will build a scientific foundation for the understanding of new phenomena in nanoscale spin-controlled devices. The PIs industrial and multidisciplinary interactions will be very beneficial in advancing research as well as in educating students. This study will also provide fundamental guidelines in the atomic-scale control of nanoscale systems such as ferroelectrics and oxide-semiconductor integration that are important for next-generation technology.
PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH
Chen, YB; Katz, MB; Pan, XQ; Folkman, CM; Das, RR; Eom, CB. "Microstructure and strain relaxation of epitaxial PrScO3 thin films grown on (001) SrTiO3 substrates," APPLIED PHYSICS LETTERS, v.91, 2007.
Dmitry Ruzmetov, Yongho Seo, Land J. Belenky, D.M. Kim, Xianglin Ke, Haiping Sun, Venkat Chandrasekhar, Chang-Beom Eom, Mark S. Rzchowski, Xiaoqing Pan. "Epitaxial Magnetic Perovskite Nanostructures," Advanced Materials, v.17, 2005, p. 2869.
Guus Rijnders, Dave H. A. Blank, Junghoon Choi, and Chang-Beom Eom. "Enhanced surface diffusion through termination conversion during epitaxial SrRuO3 growth," Appl. Phys. Lett., v.84, 2004, p. 5051.
J. Park, S.J. Oh, J.H. Park, and C. B. Eom. "Electronic structure of (Sr,Ca)RuO3 films studied by photemssion and x-ray absorption spectroscopy," Physical Review B, v.69, 2004, p. 085108.
J.S. Lee, Y.S. Lee, T.W. Noh, S. Nakatsuji, H. Fukazawa, R.S. Perry, Y. Maeno, Y. Yoshida, S.I. Ikeda, J.J. Yu, C.B. Eom . "Bond-length Dependence of Charge-transfer Excitations and Stretch Phonon Modes in Perovskite Ruthenates: Evidence of Strong p-d Hybridization Effects," Phys. Rev. B, v.70, 2004, p. 085103.
K. J. Choi, M. Biegalski, Y. L. Li, A. Sharan, J. Schubert, R. Uecker, P. Reiche, Y. B. Chen, X. Q. Pan, V. Gopalan, L.-Q. Chen, D. G. Schlom, and C. B. Eom. "Enhancement of Ferroelectricity in Strained BaTiO3 Thin Film," Science, v.306, 2004, p. 1005.
Kamal, S; Kim, DM; Eom, CB; Dodge, JS. "Terahertz-frequency carrier dynamics and spectral weight redistribution in the nearly magnetic metal CaRuO3," PHYSICAL REVIEW B, v.74, 2006.
L.J. Belenky, X. Ke, M. S. Rzchowski, C.B. Eom. "Epitaxial La0.67Sr0.33MnO3/La0.67Ba0.33MnO3 Superlattice," Journal of Applied Physics, v.97, 2005, p. 10J107.
M.S. Rzchowski and R. Joynt. "Magnetic domain walls in strongly-correlated system," Europhysics Letters, v.67, 2004, p. 287.
R.R. Das, D.M. Kim, S.H. Baek, F. Zavaliche, S.Y. Yang, X. Ke, S.K. Streiffer, M.S. Rzchowski, R. Ramesh, and C.B. Eom. "Synthesis and Properties of Epitaxial BiFeO3 Thin Films Grown by Sputtering," Appl. Phys. Lett., v.88, 2006, p. 242908.
X. Ke, L.J. Belenky, C.B. Eom, M.S. Rzchowski. "Antiferrornagnetic Exchange-bias in Epitaxial Ferromagnetic La0.67 Sr 0.33MnO3/SrRuO3 Bilayers," J. Appl. Phys., v.97, 2005, p. 10K115.
X. Ke, M.S. Rzchowksi, L.J. Belenky, and C.B Eom. "Positive exchange-bias in ferromagnetic LSMO/SRO bilayers," Applied Physics Letters, v.84, 2004, p. 5458.
Zavaliche, F; Yang, SY; Zhao, T; Chu, YH; Cruz, MP; Eom, CB; Ramesh, R. "Multiferroic BiFeO3 films: domain structure and polarization dynamics," PHASE TRANSITIONS, v.79, 2006, p. 991-1017.
Zhao, T; Scholl, A; Zavaliche, F; Lee, K; Barry, M; Doran, A; Cruz, MP; Chu, YH; Ederer, C; Spaldin, NA; Das, RR; Kim, DM; Baek, SH; Eom, CB; Ramesh, R. "Electrical control of antiferromagnetic domains in multiferroic BiFeO3 films at room temperature," NATURE MATERIALS, v.5, 2006, p. 823-829.